Abstract:
In this work, titanium dioxide (TiO2) nanoparticles were functionalized with maleic anhydride
(MA), using a non-polar (toluene) and polar protic (ethanol) solvents. The concentrations of MA in
the reaction were varied to obtain the desired degree of functionalization. The samples were characterized
with Fourier Transform Infrared Spectroscopy (FTIR), Diffuse Reflectance UV-Vis Spectroscopy
(DRS), Thermal Analysis (TGA-DTA) and Nitrogen Adsorption (BET). The physical adsorption
of organic molecules was eliminated by washing a number of times in water. Chemical
stability between solid-organic phases was confirmed by TOC and thermal analysis. FT-IR and DRS
results clearly show the chemical adsorption of MA on the TiO2. The UV-Vis spectroscopy is
claimed to be a suitable technique to determine the achievement of TiO2 functionalization. Two
different adsorptions geometries of MA were proposed. The presence of MA on the surface TiO2
increases the band gap. These results imply that TiO2 can be excited with less energy and increase
the absorption of light in the visible region. The effectiveness of the functionalized nanoparticles
to interact with organic materials is currently being studied with the intention of applying them in
the energy and environmental sanitation fields.
